Ultrafast spectroscopic study of aggregation-induced emission (AIE) materials
Project Description
This project aims to elucidate the excited-state dynamics of aggregation-induced emission (AIE) materials using ultrafast spectroscopic techniques, including femtosecond transient absorption (TA) and time-resolved fluorescence spectroscopy. By systematically investigating AIE-active molecules (e.g., tetraphenylethene derivatives) in dispersed and aggregated states, we will resolve the temporal evolution of non-radiative decay pathways, intersystem crossing rates, and exciton migration dynamics. Key objectives include correlating aggregation-dependent spectral shifts with excited-state lifetimes, identifying structural motifs that enhance radiative transitions, and quantifying the role of restricted intramolecular motion in emission enhancement. These mechanistic insights will advance the rational design of AIE materials with tailored photophysical properties for applications in optoelectronics, bioimaging, and sensing technologies. Experimental data will be complemented by computational modeling to establish structure-dynamics-function relationships, addressing critical gaps in understanding how supramolecular architectures govern ultrafast photophysical behavior.
Supervisor
CHEN, Tengteng
Quota
5
Course type
UROP1000
UROP1100
UROP2100
UROP3100
UROP3200
UROP4100
Applicant's Roles
The student will synthesize the nanomaterials and test them optical properties at ground states. The student will then learn how to carry out the fs-TA spectroscopy and time-resolved fluorescence spectroscopy independently. The student will work under the supervision of the PI, Prof. Tengteng Chen, and a PG student who will help him acclimate to the lab environment. The student will provide regular reports to Prof. Tengteng Chen.
Applicant's Learning Objectives
The student will learn:
-photophysical properties of AIE materials
-nanoaggregation synthesis and characterization
-working with advanced ultrafast spectroscopies: measurements and instrumentation
-how to work efficiently on a research project and project management skills
-photophysical properties of AIE materials
-nanoaggregation synthesis and characterization
-working with advanced ultrafast spectroscopies: measurements and instrumentation
-how to work efficiently on a research project and project management skills
Complexity of the project
Challenging